Migration of methylethynyl group in a long-lived carbocation.

نویسندگان

  • George E Salnikov
  • Alexander M Genaev
  • Vladimir A Bushmelev
  • Vyacheslav G Shubin
چکیده

Degenerate 1,2-shift of methylethynyl group in long-lived 9,10-dimethyl-9-methylethynyl-phenanthrenium ion has been detected by NMR. This is the first example of ethynyl migration in a long-lived carbocation.

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عنوان ژورنال:
  • Organic & biomolecular chemistry

دوره 11 9  شماره 

صفحات  -

تاریخ انتشار 2013